Particulated PAH and nitrated-PAM (N-PAH) have been measured in urban
areas of Pome and Milan to assess the exposure of the population to ca
rcinogenic and mutagenic compounds. We found that the index of benz(a)
pyrene equivalence of carcinogenic power and the levels of 1-nitropyre
ne and 2-nitrofluoranthene might represent a genotoxic risk for human
health even when benz(a)pyrene does not exceed the reference levels es
tablished by Italian law. A new couple of indices (1-nitropyrene and 2
-nitrofluoranthene content) is proposed to account for the risk arisin
g from N-PAH emitted from vehicle exhaust gas or produced by photochem
ical reactions.