SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [TP(BU-T)(2)]GAS - A TERMINAL GALLIUM SULFIDE COMPLEX IN A SYSTEM FOR WHICH THE INDIUM COUNTERPART IS A TETRASULFIDO DERIVATIVE, [TP(BU-T)(2)]IN(ETA(2)-S-4)

Authors
KUCHTA MC PARKIN G
Citation
Mc. Kuchta et G. Parkin, SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [TP(BU-T)(2)]GAS - A TERMINAL GALLIUM SULFIDE COMPLEX IN A SYSTEM FOR WHICH THE INDIUM COUNTERPART IS A TETRASULFIDO DERIVATIVE, [TP(BU-T)(2)]IN(ETA(2)-S-4), Journal of the Chemical Society. Dalton transactions, (14), 1998, pp. 2279-2280
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
14
Year of publication
1998
Pages
2279 - 2280
Database
ISI
SICI code
0300-9246(1998):14<2279:SASCO[>2.0.ZU;2-8
Abstract
The synthesis of the terminal gallium sulfide complex [Tp(But2)]GaS vi a the reaction of monovalent [Tp(But2)]Ga with elemental sulfur provid es a striking contrast with the formation of the tetrasulfido derivati ve [Tp(But2)]In(eta(2)-S-4) in the indium system; such an observation provides a strong indication that gallium exhibits a greater tendency to partake in multiple bonding than does indium.