SYNTHESIS AND CHARACTERIZATION OF NEW TITANIUM HEXANUCLEAR OXO CARBOXYLATO ALKOXIDES - MOLECULAR-STRUCTURE OF [TI-6(MU(3)-O)(6)-(MU-O2CC6H4OPH)(6)(OET)(6)]

Authors
PAPIERNIK R HUBERTPFALZGRAF LG VAISSERMANN J GONCALVES MCHB
Citation
R. Papiernik et al., SYNTHESIS AND CHARACTERIZATION OF NEW TITANIUM HEXANUCLEAR OXO CARBOXYLATO ALKOXIDES - MOLECULAR-STRUCTURE OF [TI-6(MU(3)-O)(6)-(MU-O2CC6H4OPH)(6)(OET)(6)], Journal of the Chemical Society. Dalton transactions, (14), 1998, pp. 2285-2287
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
14
Year of publication
1998
Pages
2285 - 2287
Database
ISI
SICI code
0300-9246(1998):14<2285:SACONT>2.0.ZU;2-E
Abstract
The reaction between Ti(OR)(4) (R = Et or Pr-i) and 2-phenoxybenzoic a cid in refluxing toluene led to [Ti-6(mu(3)-O)(6)(mu-O2CC6H4OPh)(6)(OR )(6)]; its structure corresponds to an assembly of two staggered trian gular units sharing six edges (actually the mu(3)-O ligands) and conne cted via the carboxylate ligands.