SYNTHESIS AND CHARACTERIZATION OF NEW TITANIUM HEXANUCLEAR OXO CARBOXYLATO ALKOXIDES - MOLECULAR-STRUCTURE OF [TI-6(MU(3)-O)(6)-(MU-O2CC6H4OPH)(6)(OET)(6)]
R. Papiernik et al., SYNTHESIS AND CHARACTERIZATION OF NEW TITANIUM HEXANUCLEAR OXO CARBOXYLATO ALKOXIDES - MOLECULAR-STRUCTURE OF [TI-6(MU(3)-O)(6)-(MU-O2CC6H4OPH)(6)(OET)(6)], Journal of the Chemical Society. Dalton transactions, (14), 1998, pp. 2285-2287
The reaction between Ti(OR)(4) (R = Et or Pr-i) and 2-phenoxybenzoic a
cid in refluxing toluene led to [Ti-6(mu(3)-O)(6)(mu-O2CC6H4OPh)(6)(OR
)(6)]; its structure corresponds to an assembly of two staggered trian
gular units sharing six edges (actually the mu(3)-O ligands) and conne
cted via the carboxylate ligands.