The use of environmental isotopes as tracers in the hydrosphere is inc
reasing as analytical instrumentation improves and more applications a
re discovered. There exists still misconceptions on the role of isotop
es in resolving hydrology problems. Naturally occurring isotopes in th
e environment describe hydrological processes, estimate ages, fingerpr
int sources and pathways, yet are not subject to the regulatory restra
ints of artificial isotope injections nor the Limited extent of many c
hemical tracers, particularly dyes and particulates. A shea review is
presented for practicing hydrologists on the basis for employing stabl
e and radioactive isotopes and a synopsis of recent isotope hydrology
applications is provided. Special focus is presented on the emergent r
ole of water isopopes (O-18, H-2, H-3) in wet-weather flow research in
urban watersheds. A brief technical approach for an experimental site
in the Mill Creek Watershed, Ohio is outlined.