J. Polit et al., RAMAN-SCATTERING AND FAR-INFRARED REFLECTION-ABSORPTION SPECTRA OF THE 4-COMPONENT SOLID-SOLUTION ZNXCDYHG1-X-YTE, Physica status solidi. b, Basic research, 208(1), 1998, pp. 21-30
The Raman spectra for three compositions of ZnxCdyHg1-x-yTe (ZMCT) sol
id solution were obtained at 300 K. The experimental method allowed us
to observe TO-phonon lines. The comparison of the spectra for composi
tions with x = 0.02, y = 0.7 and x = 0.12, y = 0.17 shows the appearan
ce of additional lines at 163 and 175 cm(-1) besides two lines which a
re observed in the range 120 to 150 cm(-1). Far Infrared Reflection Sp
ectra (FIRS) were obtained for five compositions. Theoretical models f
or three modes of the four-component solid solution were constructed f
or the interpretation of the FIRS spectra of ZMCT. We obtained good ag
reement between the results of RS and FIRS which allowed us to determi
ne the LO- and TO-phonon frequencies for HgTe-, CdTe- and ZnTe-like la
ttices.