F. Nieto et C. Uebing, FINITE-SIZE DEPENDENCE OF THE TRACER SURFACE-DIFFUSION COEFFICIENT NEAR A 2ND-ORDER PHASE-TRANSITION, Berichte der Bunsengesellschaft fur Physikalische Chemie, 102(7), 1998, pp. 974-977
Citations number
15
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
We investigate the finite size dependences of the tracer surface diffu
sion coefficient in the vicinity of a second order phase transition. F
or this purpose, we use a lattice gas model of repulsively interacting
particles on a square lattice. For all lattice sizes L studied, the t
racer diffusion coefficient, D-t, is a smooth function of temperature.
There are no anomalies in the direct temperature dependence of D-t ne
ar the critical temperature T-c. However, its derivative, dD(t)/d(1/k(
B)T), exhibits cusp-like anomalies which are largely pronounced for la
rge lattice sizes.