SYNTHESIS AND STRUCTURE OF TRIS[(2-ALKOXYMETHYL)PHENYL]GERMANES AND TRIS[(2-METHYLTHIOMETHYL)PHENYL]GERMANE

Authors
TAKEUCHI Y YAMAMOTO H TANAKA K OGAWA K HARADA J IWAMOTO T YUGE H
Citation
Y. Takeuchi et al., SYNTHESIS AND STRUCTURE OF TRIS[(2-ALKOXYMETHYL)PHENYL]GERMANES AND TRIS[(2-METHYLTHIOMETHYL)PHENYL]GERMANE, Tetrahedron, 54(33), 1998, pp. 9811-9822
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
54
Issue
33
Year of publication
1998
Pages
9811 - 9822
Database
ISI
SICI code
0040-4020(1998)54:33<9811:SASOTA>2.0.ZU;2-Q
Abstract
Tris[(2-alkoxymethyl)phenyl]germanes and tris[(2-methylthiomethyl)phen yl]germane were prepared and their structures were investigated by mea ns of X-ray crystallographic: analysis and Ge-73 NMR spectra, which in dicated incipient dative bonding between germanium and sulfur or oxyge n atoms to make the germanium atom hexavalent and heptavalent, respect ively. (C) 1998 Elsevier Science Ltd. All rights reserved.