THE 1ST HYDRIDES OF A PHOSPHORUS SULFIDE CAGE - NUCLEAR-MAGNETIC-RESONANCE EVIDENCE FOR ALPHA-TETRAPHOSPHORUS TRISULFIDE HYDRIDE COMPOUNDS

Authors
TATTERSHALL BW KENDALL NL
Citation
Bw. Tattershall et Nl. Kendall, THE 1ST HYDRIDES OF A PHOSPHORUS SULFIDE CAGE - NUCLEAR-MAGNETIC-RESONANCE EVIDENCE FOR ALPHA-TETRAPHOSPHORUS TRISULFIDE HYDRIDE COMPOUNDS, Journal of the Chemical Society. Dalton transactions, (21), 1993, pp. 3163-3167
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
21
Year of publication
1993
Pages
3163 - 3167
Database
ISI
SICI code
0300-9246(1993):21<3163:T1HOAP>2.0.ZU;2-F
Abstract
The hydrides alpha-P4S4(H)R (R = H, I, NMePh or SPh) have been prepare d in solution by the reaction of alpha-P4S3I2 or of the corresponding alpha-P4S3(I)R with SnBun3H, and identified by P-31 NMR spectroscopy. The compounds were unstable and not isolated. Ab initio molecular orbi tal calculations of geometry have been carried out for alpha-P4S3H2, a lpha-P4S3(NMe2)2 and alpha-P4S3H (NMe2).