Rjom. Hoofman et al., ANISOTROPY OF THE CHARGE-CARRIER MOBILITY IN POLYDIACETYLENE CRYSTALS, The Journal of chemical physics, 109(5), 1998, pp. 1885-1893
The anisotropic mobility of excess charge carriers in pure and mixed c
rystals of two polydiacetylene derivatives was determined;The charge c
arriers were produced by pulsed irradiation and.detected by time-resol
ved measurement of the microwave conductivity. The charge-carrier mobi
lity was measured as a function of the orientation of the polymer back
bone in the crystal with respect to the probing electric microwave fie
ld. A lower limit:in the intrinsic anisotropy;in the charge-carrier mo
bility was found to be 15 in favor of charge transport in the directio
n of the polymer backbone as compared to the transverse direction for
polydiacetylene-(bis p-fluorobenzene Sulfonate) (pFBS), while value of
90 was found for polydiacetylene-(bis p-toluene sulfonate) (pTS) and
the 50:50 pTS/FBS copolymer, A lower limit of the change-carrier mobil
ity along the backbone of 3 cm(2)/V s was found for both pTS and pFBS.
The charge-carrier mobility in the copolymer; was found;to be one old
er of magnitude lower than in the pure polymers. (C) 1998 American Ins
titute of Physics.