THE INTERACTION OF N,N,N',N'-TETRAMETHYLPHOSPHORIC TRIAMIDE WITH CHLORAL - PHOSPHORUS-NITROGEN FISSION-PRODUCTS AND THE X-RAY CRYSTAL-STRUCTURE OF '-(2,2,2-TRICHLORO-1-DIMETHYLAMINOETHYL)PHOSPHORIC TRIAMIDE

Authors
HUDSON HR MCPARTLIN M MAVROMMATIS CN PIANKA M
Citation
Hr. Hudson et al., THE INTERACTION OF N,N,N',N'-TETRAMETHYLPHOSPHORIC TRIAMIDE WITH CHLORAL - PHOSPHORUS-NITROGEN FISSION-PRODUCTS AND THE X-RAY CRYSTAL-STRUCTURE OF '-(2,2,2-TRICHLORO-1-DIMETHYLAMINOETHYL)PHOSPHORIC TRIAMIDE, Phosphorus, sulfur and silicon and the related elements, 127, 1997, pp. 39-48
Citations number
29
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
127
Year of publication
1997
Pages
39 - 48
Database
ISI
SICI code
1042-6507(1997)127:<39:TIONTW>2.0.ZU;2-T
Abstract
The interaction of N,N,N',N'-tetramethylphosphoric triamide with chlor al gives dimethylformamide, chloroform, and a complex mixture of phosp horus-containing products, amongst which N',N'-tetramethyl-N''-(2,2,2- trichloro-1-dimethyl) phosphoric triamide was characterized by single crystal X-ray diffraction. Dimethylamino(imino)oxophosphorane is postu lated as a tricoordinate phosphorus (V) by-product, which undergoes ol igomerization or reaction with other components of the reaction system .