ISOMERIZATION AND FRAGMENTATION OF METASTABLE SECONDARY AMINE RADICALCATIONS

Authors
PETERSEN AC HAMMERUM S
Citation
Ac. Petersen et S. Hammerum, ISOMERIZATION AND FRAGMENTATION OF METASTABLE SECONDARY AMINE RADICALCATIONS, Acta chemica Scandinavica, 52(8), 1998, pp. 1045-1050
Citations number
29
Categorie Soggetti
Chemistry,Biology
Journal title
Acta chemica Scandinavica → ACNP
ISSN journal
0904213X
Volume
52
Issue
8
Year of publication
1998
Pages
1045 - 1050
Database
ISI
SICI code
0904-213X(1998)52:8<1045:IAFOMS>2.0.ZU;2-7
Abstract
Metastable straight-chain secondary amine radical cations isomerize pr ior to unimolecular fragmentation by reversible hydrogen atom abstract ion/exchange and by 1,2-migration of RCH2NH2 in intermediate beta-dist onic isomers.