M. Merawa et A. Dargelos, DYNAMIC POLARIZABILITIES AND VAN-DER-WAALS COEFFICIENTS FOR ALKALI ATOMS LI, NA AND ALKALI DIMER MOLECULES LI-2, NA-2 AND NALI, Journal de chimie physique et de physico-chimie biologique, 95(7), 1998, pp. 1711-1730
The present paper gives an account of investigations of the polarizabi
lity of the alkali atoms Li, Na, diatomics homonuclear and heteronucle
ar Li-2, Na-2 and NaLi at SCF (Self Consistent Field) level of approxi
mation and at correlated level, using a time Time-Dependent Gauge Inva
riant method (TDGI). Our static polarizability values agree with the b
est experimental and theoretical determinations. The Van der Waals C-6
coefficients for the atom-atom, atom-dimer and dimer-dimer interactio
ns have been evaluated.