REGIOSELECTIVE ADDITIONS TO PI-ALLYL METAL-COMPLEXES

Authors
KRAFFT ME FU Z PROCTER MJ WILSON AM DASSE OA HIROSAWA C
Citation
Me. Krafft et al., REGIOSELECTIVE ADDITIONS TO PI-ALLYL METAL-COMPLEXES, Pure and applied chemistry, 70(5), 1998, pp. 1083-1090
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
70
Issue
5
Year of publication
1998
Pages
1083 - 1090
Database
ISI
SICI code
0033-4545(1998)70:5<1083:RATPM>2.0.ZU;2-D
Abstract
Highly regioselective additions to allylic acetates, catalyzed by pall adium (0), can be achieved by incorporation of a thioether or tertiary amine on the substrate. Reactions with malonate anion are highly sele ctive for the terminus of the allyl moiety proximal to the heteroatom.