DITHIOCARBAMATE-FUNCTIONALIZED DENDRIMERS AS LIGANDS FOR METAL-COMPLEXES

Authors
MCCUBBIN QJ STODDART FJ WELTON T WHITE AJP WILLIAMS DJ
Citation
Qj. Mccubbin et al., DITHIOCARBAMATE-FUNCTIONALIZED DENDRIMERS AS LIGANDS FOR METAL-COMPLEXES, Inorganic chemistry, 37(15), 1998, pp. 3753-3758
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
15
Year of publication
1998
Pages
3753 - 3758
Database
ISI
SICI code
0020-1669(1998)37:15<3753:DDALFM>2.0.ZU;2-P
Abstract
Zeroth- and first-generation poly(amido)amine dendrimers have been fun ctionalized with dithiocarbamate end groups and reacted with ruthenium complexes, to form metallodendrimers. Monomeric ruthenium dithiocarba mate complexes were also prepared as model compounds and their spectro scopic data compared with those of the metallodendrimers. The novel co mpounds were characterized using NMR spectroscopy (H-1 and C-13) and m ass spectrometry. The compound [Ru(S2CNMe2)(PPh3)(eta(5)-C5H5)] has al so been characterized crystallographically.