2-DIMENSIONAL SHEETS OF RUGGED HEXAGONAL GRIDS OF ANS-OXEN)(3)(MU(3)-OH)(2)(H2O)(2)](N)(4N-OXAMIDATE (OXEN) AND MU(3)-OH- GROUPS() WITH COPPER(II) BRIDGED BY TRANS)

Authors
CHEN ZN ZHANG HX SU CY ZHOU ZY ZHENG KC KANG BS
Citation
Zn. Chen et al., 2-DIMENSIONAL SHEETS OF RUGGED HEXAGONAL GRIDS OF ANS-OXEN)(3)(MU(3)-OH)(2)(H2O)(2)](N)(4N-OXAMIDATE (OXEN) AND MU(3)-OH- GROUPS() WITH COPPER(II) BRIDGED BY TRANS), Inorganic chemistry, 37(15), 1998, pp. 3877
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
15
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:15<3877:2SORHG>2.0.ZU;2-1
Abstract
The coordination polymeric cation of [Cu-6(trans-oxen)(3)(mu(3)-OH)(2) (H2O)(2)](n)Br-4n . 3nH(2)O exhibits a two-dimensional sheetlike frame work with rugged hexagonal grids of copper(II) ions bridged by alterna ting trans-oxamidate and mu(3)-OH- groups producing antiferromagnetic interactions; The polymeric cation, anions Br-, and H2O molecules coor dinated and solvated are connected to one another via a variety of H-b onded linkages to produce a three-dimensional extended network.