CLUSTER-MODELS IN THE QUANTUM-CHEMICAL ANALYSIS OF THE COORDINATION OF IMIDAZOLINE NITROXIDES ON THE SURFACE OF SILICA-GEL

Authors
CHUVYLKIN ND TOKMACHEV AM FIONOV AV LUNINA EV
Citation
Nd. Chuvylkin et al., CLUSTER-MODELS IN THE QUANTUM-CHEMICAL ANALYSIS OF THE COORDINATION OF IMIDAZOLINE NITROXIDES ON THE SURFACE OF SILICA-GEL, Mendeleev communications (Print), (3), 1998, pp. 90-93
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications (Print) → ACNP
ISSN journal
09599436
Issue
3
Year of publication
1998
Pages
90 - 93
Database
ISI
SICI code
0959-9436(1998):3<90:CITQAO>2.0.ZU;2-K
Abstract
A 'minimal' cluster quantum-chemical model of paired acid sites on the surface of SiO2 is presented; the model provides adequate explanation of the radiospectroscopic and thermochemical data available on the tw o-centre and one-centre adsorption of nitroxide probes on the silica s urface.