CATALYSIS OF ENE REACTIONS BY LITHIUM PERCHLORATE

Authors
DAVIES AG KINART WJ
Citation
Ag. Davies et Wj. Kinart, CATALYSIS OF ENE REACTIONS BY LITHIUM PERCHLORATE, Perkin transactions. 2, (11), 1993, pp. 2281-2284
Citations number
34
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
11
Year of publication
1993
Pages
2281 - 2284
Database
ISI
SICI code
0300-9580(1993):11<2281:COERBL>2.0.ZU;2-W
Abstract
The ene reaction of some allylic hydrocarbons, and the metallo-ene rea ction of some allyltin compounds, with 1,3,4-triazoline-2,5-diones or with diethyl azodicarboxylate as enophiles, in diethyl ether are stron gly catalysed by lithium perchlorate. Azobenzene, on the other hand, r eacts slowly with alkyltin compounds, undergoing hydrostannation. The reaction of cholesterol or of tributylallyltin with singlet oxygen is subject to a smaller catalysis.