Despite many years of research, the detailed atomic structure of many
important carbon materials remains poorly understood. In particular, t
he structure of those carbons which can not be transformed into graphi
te by high temperature heat treatment has never been clearly establish
ed. These non-graphitising carbons are of considerable commercial impo
rtance in a variety of fields, and a better understanding of their str
ucture is clearly needed. Recently, it has been suggested that non-gra
phitising carbons may have a microstructure which is related to that o
f fullerenes. In the present paper, the evidence for this will be cons
idered in detail and the advantages of the new model over previous mod
els of non-graphitising carbons will be discussed. As well as micropor
ous non-graphitising carbons, other forms of carbon including glassy c
arbon and carbon fibres will be considered.