Methyl esters of sunflowerseed oil fatty acids can be produced satisfa
ctorily by reaction with the oil in situ. Experiments were designed to
determine how variations in molar ratio of methanol to oil, amount of
acidic catalyst, and time and temperature of reaction affected the yi
eld and properties of esters. Good results were obtained in mild react
ion conditions (temperature 30 degrees C) with a strong acidic catalys
t and high molar ratio The fatty ester composition and properties of t
he products derived from reactions in situ is essentially the same as
that from conventional tranesterification of the pre-extracted oil. It
is of obvious importance that the products obtained by in situ reacti
on be as suitable as a diesel fuel substitute as those derived from th
e conventional treatment. (C) 1998 Published by Elsevier Science Ltd.
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