J. Otsuki et al., ENERGY-GAP DEPENDENCE OF ELECTRON-TRANSFER RATES IN PORPHYRIN-IMIDE SUPRAMOLECULAR ASSEMBLIES, Chemical communications, (15), 1998, pp. 1515-1516
The energy gap dependence of the rate of electron transfer has been re
vealed for donor-acceptor supramolecular assemblies composed of zinc-t
etraphenylporphyrin and a series of spacer-acceptor conjugate molecule
s which are structurally similar but with varying redox potentials.