SYNTHESIS AND STRUCTURE OF [((BUP)-P-T)(2)H)K-CENTER-DOT-PMDETA](2), CONTAINING AN ORGANO DIPHOSPHIDO LIGAND [PMDETA = (ME2NCH2CH2)(2)NME]

Authors
BESWICK MA HOPKINS AD KERR LC MOSQUERA MEG PALMER JS RAITHBY PR ROTHENBERGER A STALKE D STEINER A WHEATLEY AEH WRIGHT DS
Citation
Ma. Beswick et al., SYNTHESIS AND STRUCTURE OF [((BUP)-P-T)(2)H)K-CENTER-DOT-PMDETA](2), CONTAINING AN ORGANO DIPHOSPHIDO LIGAND [PMDETA = (ME2NCH2CH2)(2)NME], Chemical communications, (15), 1998, pp. 1527-1528
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
15
Year of publication
1998
Pages
1527 - 1528
Database
ISI
SICI code
1359-7345(1998):15<1527:SASO[C>2.0.ZU;2-L
Abstract
Reduction of [(BuP)-P-t](4\) with K metal (1:5 equiv,) followed by the addition of pmdeta and stoichiometric hydrolysis gives [(((BuP)-P-t)( 2)H}K . pmdeta](2), a unique complex containing a [(BuP)-P-t(H)PBut](- ) anion ligand homologous with a phosphido anion (R2P-).