PHOSPHA-WITTIG REACTIONS USING ISOLABLE PHOSPHORANYLIDENEPHOSPHINES ARP=PR3 (AR = 2,6-MES(2)C(6)H(3) OR 2,4,6-BU(T)3C(6)H(2))

Citation
S. Shah et Jd. Protasiewicz, PHOSPHA-WITTIG REACTIONS USING ISOLABLE PHOSPHORANYLIDENEPHOSPHINES ARP=PR3 (AR = 2,6-MES(2)C(6)H(3) OR 2,4,6-BU(T)3C(6)H(2)), Chemical communications, (15), 1998, pp. 1585-1586
Citations number
17
Categorie Soggetti
Chemistry
Journal title
ISSN journal
13597345
Issue
15
Year of publication
1998
Pages
1585 - 1586
Database
ISI
SICI code
1359-7345(1998):15<1585:PRUIPA>2.0.ZU;2-S
Abstract
Phosphoranylidenephosphines DmpP=PMe3 (1a, Dmp = 2,6-Mes(2)C(6)H(3)) a nd MesP=PMe3 (1b, Mes* = 2,4,6-(Bu3C6H2)-C-t) act as 'Phospha-Wittig' reagents with aldehydes providing phosphaalkenes [ArP=C(H)R] in high yields.