As. Jepsen et al., CRYSTAL-STRUCTURE OF A CHIRAL NITRIDO-MANGANESE SALEN COMPLEX - THE NITROGEN ANALOG TO THE INTERMEDIATE IN THE JACOBSEN EPOXIDATION REACTION, Chemical communications, (15), 1998, pp. 1599-1600
A chiral nitrido-manganese salen complex has been synthesised and char
acterised by X-ray diffraction; the geometrical and electronic structu
re of the complex are discussed in relation to the intermediate in asy
mmetric reactions.