LONG-RANGE INDUCTION COEFFICIENTS FOR LIKE CENTROSYMMETRIC LINEAR-MOLECULES AND AN APPLICATION TO H-2-H-2

Authors
MAGNASCO V OTTONELLI M FIGARI G RUI M COSTA C
Citation
V. Magnasco et al., LONG-RANGE INDUCTION COEFFICIENTS FOR LIKE CENTROSYMMETRIC LINEAR-MOLECULES AND AN APPLICATION TO H-2-H-2, Chemical physics letters, 291(5-6), 1998, pp. 529-535
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
291
Issue
5-6
Year of publication
1998
Pages
529 - 535
Database
ISI
SICI code
0009-2614(1998)291:5-6<529:LICFLC>2.0.ZU;2-R
Abstract
The C-8 and C-10 long-range induction coefficients for two like centro symmetric linear molecules are derived explicitly using the irreducibl e properties of spherical tensor operators. An application to the H-2- H-2 system shows that whereas the isotropic induction coefficients are 50-100 times smaller than dispersion, the induction anisotropies gamm a(n) are always larger than the corresponding dispersion anisotropies. (C) 1998 Elsevier Science B.V. All rights reserved.