TETRAMETHYLSILANE AS REAGENT GAS - MASS-SPECTRA OF NITROCARBOXYLIC ACID-ESTERS AND NITROALCOHOLS

Authors
KADENTSEV VI KOLOTYRKINA NG STOMAKHIN AA CHIZHOV OS IOFFE SL LYAPKALO IM DILMAN AD TISHKOV AA
Citation
Vi. Kadentsev et al., TETRAMETHYLSILANE AS REAGENT GAS - MASS-SPECTRA OF NITROCARBOXYLIC ACID-ESTERS AND NITROALCOHOLS, Russian chemical bulletin, 47(6), 1998, pp. 1225-1228
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
47
Issue
6
Year of publication
1998
Pages
1225 - 1228
Database
ISI
SICI code
1066-5285(1998)47:6<1225:TARG-M>2.0.ZU;2-U
Abstract
Nitrocarboxylic acid esters and nitroalcohols react with trimethylsily l cation in the gas phase under conditions of chemical ionization to f orm stable [M+SiMe3](+) ions. The pathways of their fragmentation were established and characteristic distinctions in the mass spectra cause d by mutual arrangement of functional groups were found.