The modulational instability development of Langmuir waves is investig
ated in highly collisional plasmas where the characteristic frequency
OMEGA of the modulated perturbations is much less than nu(eff), the ef
fective electron collision frequency. It is demonstrated that the modu
lational instability for the situation considered is mostly determined
by collisional effects (differential Joule heating nonlinearity), in
contrast to the well-known modulational instability in collisionless p
lasmas (where ponderomotive force nonlinearity dominates). Rates and t
hresholds of the instability are found in various limits. The modulati
onal instability is most effective when the angles between a pump wave
vector and wave vectors of the modulational perturbations are of orde
r unity.