THE DIHYDROGEN SULFIDE (C5ME5)2ZR(SH)2, S YNTHESIS AND REACTIVITY - REEXAMINATION OF THE H-1-NMR CHARACTERISTICS OF ITS POLYSULFIDE DERIVATIVES

Authors
BROUSSIER R RIGOULET M AMARDEIL R DELMAS G GAUTHERON B
Citation
R. Broussier et al., THE DIHYDROGEN SULFIDE (C5ME5)2ZR(SH)2, S YNTHESIS AND REACTIVITY - REEXAMINATION OF THE H-1-NMR CHARACTERISTICS OF ITS POLYSULFIDE DERIVATIVES, Phosphorus, sulfur and silicon and the related elements, 82(1-4), 1993, pp. 55-60
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
82
Issue
1-4
Year of publication
1993
Pages
55 - 60
Database
ISI
SICI code
1042-6507(1993)82:1-4<55:TDS
Abstract
The thermally stable dihydrogenosulfide (C5Me5)2Zr(SH)2 (1) has been o btained from the corresponding dichloride (2) and hydrogen sulfide in the presence of triethylamine. 1 reacts with sulfur in boiling toluene and with hydrogen sulfide at 80-degrees-C affording (C5Me5)2ZrS3. 2 c ombines to ''Li2S'' leading to the bimetallasulfane [(C5Me5),Zr(mu-S)] 2. A mixture of (C5Me5)2Zr(OH)(SH) and dihydroxyde was formed by the r eaction of water on the dihydrogenosulfide. The H-1 NMR chemical schif ts of the compounds are discussed.