REACTIONS OF ALPHA-OXYGEN SUBSTITUTED METHYLENE ACTIVE DITHIOCARBONATES, THIOCARBAMATES, AND CARBAMATES WITH HETEROCUMULENES

Authors
DOLLING W GILDENAST T
Citation
W. Dolling et T. Gildenast, REACTIONS OF ALPHA-OXYGEN SUBSTITUTED METHYLENE ACTIVE DITHIOCARBONATES, THIOCARBAMATES, AND CARBAMATES WITH HETEROCUMULENES, Phosphorus, sulfur and silicon and the related elements, 82(1-4), 1993, pp. 163-169
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
82
Issue
1-4
Year of publication
1993
Pages
163 - 169
Database
ISI
SICI code
1042-6507(1993)82:1-4<163:ROASMA>2.0.ZU;2-T
Abstract
The new compounds ethyl 4-methylthio-2-thioxo-1,3-oxathiole-5-carboxyl ate 2, ethyl thio-3-phenyl-2-thioxo-1,3-oxazoline-5-carboxylate 3, 0-1 -Cyano-2.2-bis(methylthio)vinyl N,N-dimethyl thiocarbamate 7, and I-Cy ano-2,2-bis(methylthio)vinyl N,N-dimethyl carbamate 9 are prepared by dithiocarboxylation or thiocarbamoylation of S-ethyl O-(ethoxycarbonyl methyl) dithiocarbonate 1, N,N-Dimethylthiocarbamoyl-glycolonitrile 6, and N,N-Dimethylcarbamoyl-glycolonitrile 8, respectively.