SYNTHESIS AND STRUCTURES OF THE SELENOLATO-BRIDGED MERCURY CLUSTERS [HG-6(SEPH)(12)(PTBU3)(2)] AND (HPTBU3)(2)[HG-6(SEPH)(14)]

Authors
BETTENHAUSEN M FENSKE D
Citation
M. Bettenhausen et D. Fenske, SYNTHESIS AND STRUCTURES OF THE SELENOLATO-BRIDGED MERCURY CLUSTERS [HG-6(SEPH)(12)(PTBU3)(2)] AND (HPTBU3)(2)[HG-6(SEPH)(14)], Zeitschrift fur anorganische und allgemeine Chemie, 624(8), 1998, pp. 1245-1246
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
8
Year of publication
1998
Pages
1245 - 1246
Database
ISI
SICI code
0044-2313(1998)624:8<1245:SASOTS>2.0.ZU;2-R
Abstract
The reaction of HgCl2 with PtBu3 and PhSeSiMe3 yields [Hg-6(SePh)(12)( PtBu3)(2)] (1) and (HPtBu3)(2)[Hg-6(SePh)(14)](2). X-ray structural an alysis of the compounds shows them to have similar Hg-Se cages with di storted tetrahedral coordination around mercury. The cages are built u p from edge- and vertex-sharing distorted tetrahedra.