[MON(NPPH3)(3)] - A MONOMERIC NITRIDO COMPLEX OF MOLYBDENUM

Authors
DIETRICH A NEUMULLER B DEHNICKE K
Citation
A. Dietrich et al., [MON(NPPH3)(3)] - A MONOMERIC NITRIDO COMPLEX OF MOLYBDENUM, Zeitschrift fur anorganische und allgemeine Chemie, 624(8), 1998, pp. 1247-1249
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
8
Year of publication
1998
Pages
1247 - 1249
Database
ISI
SICI code
0044-2313(1998)624:8<1247:[-AMNC>2.0.ZU;2-G
Abstract
[MoN(NPPh3)(3)] (1) has been prepared from [MoCl3(N3S2)](2) and LiNPPh 3 in toluene suspension in good yields. From n-hexane/dichloromethane solutions 1 2 CH2Cl2 crystallizes as colourless single crystals, which were suitable for a crystal structure determination. I forms monomeri c molecules with a Mo equivalent to N distance of 166.6 pm for the nit rido ligand, which corresponds to a triple bond, and MoN-bonds of 193. 6 pm on average of the NPPh3--ligands, corresponding to shortened sing le bonds.