PALLADIUM-CATALYZED REACTIONS OF ACYLZIRCONOCENE CHLORIDE WITH ORGANIC HALIDES

Authors
HANZAWA Y TABUCHI N TAGUCHI T
Citation
Y. Hanzawa et al., PALLADIUM-CATALYZED REACTIONS OF ACYLZIRCONOCENE CHLORIDE WITH ORGANIC HALIDES, Tetrahedron letters, 39(34), 1998, pp. 6249-6252
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
34
Year of publication
1998
Pages
6249 - 6252
Database
ISI
SICI code
0040-4039(1998)39:34<6249:PROACW>2.0.ZU;2-X
Abstract
Palladium-catalyzed reactions of nonanoylzirconocene chloride 1 with a ryl halide, acid halides, and allylic halides gave the acylated compou nds through a nucleophilic attack of an ''unmasked'' acyl anion in fai r to excellent yields. In an analogous way, allylic acetate gave an ac yl substituted product through the reaction of 1. (C) 1998 Elsevier Sc ience Ltd. All rights reserved.