STUDIES ON RING-OPENING COPOLYMERIZATION OF GLYCOLIDE AND 2-HYDRO-2-OXO-1,3,2-DIOXAPHOSPHORINANE

Citation
Cl. Fan et al., STUDIES ON RING-OPENING COPOLYMERIZATION OF GLYCOLIDE AND 2-HYDRO-2-OXO-1,3,2-DIOXAPHOSPHORINANE, Gaodeng xuexiao huaxue xuebao, 19(5), 1998, pp. 830-832
Citations number
10
Categorie Soggetti
Chemistry
ISSN journal
02510790
Volume
19
Issue
5
Year of publication
1998
Pages
830 - 832
Database
ISI
SICI code
0251-0790(1998)19:5<830:SORCOG>2.0.ZU;2-K
Abstract
A novel kind of copolymers was synthesized by ring-opening copolymeriz ation of glycolide and 2-hydro-2-oxo-1,3,2-dioxaphosphorinane, using t riisobutylaluminium as the initiator, Their structures were confirmed by H-1 NMR and FTIR, The influence of molar ratio of monomers and time on the total conversion, copolymer composition and molecular weight w ere investigated, respectively. The crystallinity degree and cell dime nsions of the copolymers were determined by XRD.