Results of measurements of angular distributions of neutrals and ions
in low-keV Ne+ and Ne-0 collisions with a Na-covered surface are prese
nted. These results are supplemented by time of flight measurements. M
easurements of angle-resolved energy spectra of electrons are presente
d for He+ and Ne+ collisions on Na. These results are compared with th
ose obtained on other systems (Mg, Al and Si). Ion fraction measuremen
ts show that the incident ionic projectiles are neutralized during the
approach towards the surface, and then reionized due to inelastic pro
cesses occurring during binary collisions with surface atoms. Our elec
tron spectroscopy measurements show the existence of two-electron exci
tation processes. These results compared with previous gas-phase resul
ts indicate the involvement of similar primary excitation mechanisms.
These are well described within a diatomic quasi-molecular model. Seve
ral marked differences observed between the gas-phase measurements and
our electron spectra are explained by surface specific mechanisms due
to charge transfer between the projectile and the surface. (C) 1998 E
lsevier Science B.V. All rights reserved.