H. Luo et al., INHIBITION OF MILD-STEEL CORROSION BY SODIUM DODECYL BENZENE SULFONATE AND SODIUM OLEATE IN ACIDIC SOLUTIONS, Corrosion, 54(8), 1998, pp. 619-627
Citations number
15
Categorie Soggetti
Material Science","Metallurgy & Metallurigical Engineering
Inhibition of mild steel corrosion by sodium dodecyl benzene sulfonate
((C12H25C6H4SO3Na [SDBS]) and sodium oleate (CH3[CH2](7)CH=CH[CH2](7)
COONa) in acidic solutions was investigated using a potentiostat, a lo
ck-in amplifier a contact angle goniometer, a Fourier transform infrar
ed (FTIR) spectrometer, and an ultraviolet (UV)/visible spectrophotome
ter. In the presence of the organic inhibitors, the corrosion rate was
reduced significantly. Anionic SDBS was adsorbed on the positively ch
arged mild steel surface through the electrostatic attraction. However
, for sodium oleate, the soluble oleic acid (CH3[CH2](7)CH=CH[CH](7)CO
OH) chemisorbed on the steel surface at the first stage. Then, insolub
le colloid adsorbed on the chemisorbed surface through van der Waals f
orces.