O. Erlandsson et al., ELECTROCHROMIC PROPERTIES OF MANGANESE OXIDE (MNOX) THIN-FILMS MADE BY ELECTRON-BEAM DEPOSITION, Physica status solidi. a, Applied research, 139(2), 1993, pp. 451-457
Electrochromic MnO(x) thin films are prepared by using an electron bea
m technique followed by annealing post-treatment. Electrochromic prope
rties of the films are studied in three different solutions: 1M LiClO4
in propylene carbonate, KOH (pH = 10.5), and natrium borate (pH = 9.2
). The transmittance spectra of the coloured films combined with their
cyclic voltammetry curves show that the enhancement of the electrochr
omic behaviour of these films can be attributed to the insertion (or e
xtraction) of the OH- anions into (or from) the MnOx films. The best e
lectrochromic efficiency of the films is obtained in the borate electr
olyte.