M. Zweynert et al., APPLICATIONS OF MAGNELI PHASES OF TITANIUM DIOOXIDE IN ELECTROCHEMICAL TECHNOLOGY, Chemieingenieurtechnik, 70(7), 1998, pp. 827-841
Magneli phases of titanium oxides are known to have many interesting p
roperties such as a conductivity comparable to that of graphite, a hig
h level of chemical stability, and large overpotentials for gas evolvi
ng reactions. In this paper the possibilities for synthesis of pure Ma
gneli phases are reported and the influence of various experimental pa
rameters on the electrochemical properties is discussed. Several chemi
cal, electrochemical, physicochemical, and physical experiments were p
erformed. The opportunities for technological applications in the fiel
d of electroplating. in the recycling of process solutions, as support
ing substrates for electrocatalysts, and as collector materials are co
nsidered.