ENANTIOMERICALLY PURE 3-P-TOLYLSULFINYL ACROLEIN AND CROTONALDEHYDE DIMETHYLACETALS - STEREOSELECTIVE REDUCTION OF BETA-KETO-GAMMA,GAMMA-DIALKOXYSULFOXIDES

Authors
RUANO JLG MAESTRO MC SANCHEZSANCHO F
Citation
Jlg. Ruano et al., ENANTIOMERICALLY PURE 3-P-TOLYLSULFINYL ACROLEIN AND CROTONALDEHYDE DIMETHYLACETALS - STEREOSELECTIVE REDUCTION OF BETA-KETO-GAMMA,GAMMA-DIALKOXYSULFOXIDES, Tetrahedron : asymmetry, 6(9), 1995, pp. 2299-2312
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
9
Year of publication
1995
Pages
2299 - 2312
Database
ISI
SICI code
0957-4166(1995)6:9<2299:EP3AAC>2.0.ZU;2-W
Abstract
The synthesis of the title compounds by basic elimination on the O-der ivatives of unsubstituted and alpha-methylated beta-hydroxy-gamma, gam ma-dialkoxysulfoxides is reported. The study of the stereoselectivity of DIBAL and DIBAL/ZnI2 reductions of the starting beta-ketosulfoxides and their alpha-methylated derivatives is also presented.