APPLICATION OF NOVEL PHOSPHINE OXAZOLINE LIGANDS IN ASYMMETRIC ALLYLATIONS OF 4-ACYLOXY-2-PENTENE DERIVATIVES

Authors
BURGESS K PORTE AM
Citation
K. Burgess et Am. Porte, APPLICATION OF NOVEL PHOSPHINE OXAZOLINE LIGANDS IN ASYMMETRIC ALLYLATIONS OF 4-ACYLOXY-2-PENTENE DERIVATIVES, Tetrahedron : asymmetry, 9(14), 1998, pp. 2465-2469
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
14
Year of publication
1998
Pages
2465 - 2469
Database
ISI
SICI code
0957-4166(1998)9:14<2465:AONPOL>2.0.ZU;2-4
Abstract
A library of novel phosphine oxazoline ligands 2 was tested in the asy mmetric allylation of 4-acyloxy-2-pentenes 1. High throughput screenin g techniques were employed to accelerate this process. The data accumu lated allowed the extent of asymmetric induction to be correlated with the ligand substituent R and ligand-to-metal ratios. (C) 1998 Elsevie r Science Ltd. All rights reserved.