M. Bohning et J. Springer, SORPTIVE DILATION AND RELAXATIONAL PROCESSES IN GLASSY POLYMER GAS SYSTEMS - I - POLY(SULFONE) AND POLY(ETHER SULFONE), Polymer, 39(21), 1998, pp. 5183-5195
The volumetric behaviour of glassy poly(sulfone) and poly(ether sulfon
e) under gas pressures of CO2, N2O and CH4 up to 50 bar was investigat
ed at 35 degrees C using a new experimental technique based on a capac
itive distance measurement. Corresponding gas concentrations within th
e polymers were determined by gravimetric gas sorption measurements. T
he time-dependent dilation after a pressurising step reveals two disti
nct dilation modes. The analysis of the first dilation mode according
to mass transport kinetics is in good agreement with diffusion coeffic
ients from time-lag experiments, whereas the slower secondary process
has to be considered as volume relaxation resulting from the enhanced
polymer chain mobility and the stress exerted by the sorbed gas molecu
les. (C) 1998 Elsevier Science Ltd. All rights reserved.