COMPARISON OF CL-35 NQR SPECTRA BETWEEN THE MIXED-CRYSTALS K2SN1-XREXCL6 AND THE AL3-AL3+( DOPED CRYSTALS K2SNCL6)

Authors
SEO YM PELZL J DIMITROPOULUS C
Citation
Ym. Seo et al., COMPARISON OF CL-35 NQR SPECTRA BETWEEN THE MIXED-CRYSTALS K2SN1-XREXCL6 AND THE AL3-AL3+( DOPED CRYSTALS K2SNCL6), Zeitschrift fur Naturforschung. A, A journal of physical sciences, 53(6-7), 1998, pp. 552-558
Citations number
8
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
53
Issue
6-7
Year of publication
1998
Pages
552 - 558
Database
ISI
SICI code
0932-0784(1998)53:6-7<552:COCNSB>2.0.ZU;2-R
Abstract
Cl-35 Nuclear Quadrupole Resonance (NQR) has provided a valuable tool for investigating the local structure in mixed crystals K2Sn1-xRexCl6 and Al3+ doped crystals K2SnCl6:Al3+. The measured NQR line shapes and relaxation times of both kinds of impurity containing crystals in the cubic phase of the host K2SnCl6 show markedly different impurity effe cts; static impurity effects in K2Sn1-xRexCl6 and dynamic effects in K 2SnCl6:Al3+. The Cl-35 NQR spectra of K2SnCl6:Al3+ near the transition temperature (T-c) indicate the presence of pretransition of the local structure in the high temperature cubic phase.