CL-35 NQR, H-1-NMR, AND X-RAY-DIFFRACTION STUDIES IN A HYDROGEN-BONDED COMPLEX NA2PTCL6-CENTER-DOT-6H(2)O

Authors
MIYOSHI H HORIUCHI K SAKAGAMI N OKAMOTO K IKEDA R
Citation
H. Miyoshi et al., CL-35 NQR, H-1-NMR, AND X-RAY-DIFFRACTION STUDIES IN A HYDROGEN-BONDED COMPLEX NA2PTCL6-CENTER-DOT-6H(2)O, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 53(6-7), 1998, pp. 603-607
Citations number
11
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
53
Issue
6-7
Year of publication
1998
Pages
603 - 607
Database
ISI
SICI code
0932-0784(1998)53:6-7<603:CNHAXS>2.0.ZU;2-L
Abstract
The Cl-35 NQR frequencies, spin-lattice relaxation time and H-1 NMR re laxation time were measured on crystalline Na2PtCl6 . H2O at 77-350 K. The presence of three nonequivalent chlorine sites found by X-ray dif fraction measurement is in agreement with the observed three NQR lines , which have different temperature dependences attributable to differe nces in the direction of H-bonding with water molecules. The three NQR lines correspond to three kinds of chlorines with different Pt-Cl dis tances and H-bond directions.