THE FEATURES OF MOSSBAUER-SPECTRA OF HEMOGLOBIN IN RELATION TO THE QUADRUPOLE SPLITTING AND HEME IRON STEREOCHEMISTRY

Authors
OSHTRAKH MI
Citation
Mi. Oshtrakh, THE FEATURES OF MOSSBAUER-SPECTRA OF HEMOGLOBIN IN RELATION TO THE QUADRUPOLE SPLITTING AND HEME IRON STEREOCHEMISTRY, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 53(6-7), 1998, pp. 608-614
Citations number
32
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
53
Issue
6-7
Year of publication
1998
Pages
608 - 614
Database
ISI
SICI code
0932-0784(1998)53:6-7<608:TFOMOH>2.0.ZU;2-M
Abstract
Mossbauer spectra of various human ferrous hemoglobins in different li gand forms demonstrated some features such as non-lorentzian line shap e for oxyhemoglobins, narrower line width for carbonmonoxide, and vari ations of quadrupole splitting for different hemoglobins. These featur es were considered in relation to the variations of quadrupole splitti ng and heme iron stereochemistry in different hemoglobins as well as i n non-equivalent subunits of hemoglobin tetramer.