A NEW STEREOCONTROLLED ROUTE TO (-CURCUPHENOL, A PHENOLIC SESQUITERPENE FROM THE MARINE SPONGE DIDISCUS-FLAVUS())

Authors
SUGAHARA T OGASAWARA K
Citation
T. Sugahara et K. Ogasawara, A NEW STEREOCONTROLLED ROUTE TO (-CURCUPHENOL, A PHENOLIC SESQUITERPENE FROM THE MARINE SPONGE DIDISCUS-FLAVUS()), Tetrahedron : asymmetry, 9(13), 1998, pp. 2215-2217
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
13
Year of publication
1998
Pages
2215 - 2217
Database
ISI
SICI code
0957-4166(1998)9:13<2215:ANSRT(>2.0.ZU;2-3
Abstract
Using a synthetic equivalent of chiral 2-cyclopentenol, (+)-curcupheno l, a cytotoxic bisabolane type sesquiterpene isolated from the marine sponge Didiscus flavus, has been synthesized through a concurrent retr o-Diels-Alder reaction and Claisen rearrangement reaction. (C) 1998 El sevier Science Ltd. All rights reserved.