PALLADIUM-CATALYZED ASYMMETRIC REDUCTION OF ALLYLIC ESTERS WITH A NEWCHIRAL MONODENTATE LIGAND, 8-DIPHENYLPHOSPHINO-8'-METHOXY-1,1'-BINAPHTHYL

Authors
FUJI K SAKURAI M KINOSHITA T KAWABATA T
Citation
K. Fuji et al., PALLADIUM-CATALYZED ASYMMETRIC REDUCTION OF ALLYLIC ESTERS WITH A NEWCHIRAL MONODENTATE LIGAND, 8-DIPHENYLPHOSPHINO-8'-METHOXY-1,1'-BINAPHTHYL, Tetrahedron letters, 39(35), 1998, pp. 6323-6326
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
35
Year of publication
1998
Pages
6323 - 6326
Database
ISI
SICI code
0040-4039(1998)39:35<6323:PAROAE>2.0.ZU;2-T
Abstract
A new chiral monodentate ligand, 8-diphenylphosphino-8'-methoxy-1,1'-b inaphthyl (8-MeO-MOP), was used for palladium-catalyzed reduction of a llylic carbonates with formic acid. Various methylcarbonates of 3,3'-d isubstituted allylic alcohols were converted to the corresponding opti cally active 1-olefins with this ligand. (C) 1998 Elsevier Science Ltd . All rights reserved.