COPPER(II) MEDIATED REGIOSELECTIVE ACETOXYLATION OF ALLYLIC ACETATES AND 1,4-DIACETOXYLATION OF ALKENES

Authors
MACSARI I SZABO KJ
Citation
I. Macsari et Kj. Szabo, COPPER(II) MEDIATED REGIOSELECTIVE ACETOXYLATION OF ALLYLIC ACETATES AND 1,4-DIACETOXYLATION OF ALKENES, Tetrahedron letters, 39(35), 1998, pp. 6345-6348
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
35
Year of publication
1998
Pages
6345 - 6348
Database
ISI
SICI code
0040-4039(1998)39:35<6345:CMRAOA>2.0.ZU;2-1
Abstract
Copper(II) chloride in presence of lithium chloride in acetic acid oxi dizes allylic acetates with high regioselectivity. Tandem allylic C-H bond functionalization of unsubstituted alkenes could be accomplished by using copper(II) chloride / lithium chloride reagent together with catalytic amounts of palladium(II) salts. (C) 1998 Elsevier Science Lt d. All rights reserved.