Copper selenide (CuSe) was compressed in a diamond anvil cell at room
temperature up to a pressure of 52 GPa and studied using energy disper
sive x-ray diffraction and Raman spectroscopy. CuSe is nearly isostruc
tural with copper sulfide (CuS), and a previous study indicates that c
opper sulfide undergoes reversible pressure-induced amorphization at 1
8 GPa. The intensity of the x-ray diffraction peaks for CuSe decrease
slowly, however, they never completely disappear up to a pressure of 5
2 GPa. The third-order Birch-Murnaghan equation of state fit to the da
ta yields K-0 = 96.9 +/- 5.3 GPa and K-0' = 4.1 +/- 0.5. Vinet's unive
rsal equation of state yields essentially identical parameters. Raman
spectroscopy demonstrates that upon compression, the S-S bond in CuS c
ompresses differently than the Se-Se bond in CuSe, possibly accounting
fur the different high pressure behavior of these two very similar co
mpounds. (C) 1998 American Institute of Physics.