Js. Kwak et al., IMPROVEMENT OF TA DIFFUSION BARRIER PERFORMANCE IN CU METALLIZATION BY INSERTION OF A THIN ZR LAYER INTO TA FILM, Applied physics letters, 72(22), 1998, pp. 2832-2834
In order to increase the failure temperature of Ta diffusion barrier f
or Cu, we investigated the effect of insertion of a thin Zr layer into
Ta film with/without ion bombardment on Ta diffusion barrier performa
nce in Cu metallization. The insertion of a thin Zr layer into Ta film
improved barrier properties significantly when the Ta/Zr/Ta barrier l
ayers were deposited with concurrent ion bombardment. The significant
improvement of Ta diffusion barrier properties by insertion of a thin
Zr layer into Ta film with ion bombardment was attributed to the densi
fication of grain boundaries in Ta/Zr/Ta films and the formation of an
intermixing layer between Ta and Zr by ion bombardment, followed by t
he reduction of fast diffusion of Cu through Ta/Zr/Ta films. (C) 1998
American Institute of Physics.