O. Kircher et al., DECAY OF SINGLE AND DOUBLE-QUANTUM COHERENCES IN DEUTERATED GLASSY ORTHO-TERPHENYL, The Journal of chemical physics, 108(20), 1998, pp. 8550-8556
The decay of single and double quantum coherences in amorphous ortho-t
erphenyl is studied by means of deuteron NMR echo experiments near and
below the calorimetric glass transition temperature T-g. In perdeuter
ated samples a Gaussian decay for these coherences is found at low tem
peratures, in accord with theoretical predictions for random local dip
olar fields. A method is proposed to extract information about slow mo
tional processes from ordinary solid echo experiments below T-g. Partl
y deuterated ortho-terphenyl does not show a Gaussian decay. Simple mo
del calculations show that this observation indicates the importance o
f correlations of the local dipolar fields in the presence of protons.
(C) 1998 American Institute of Physics. [S0021-9606(98)51820-X].