Experimental measurements of the shifts of ruby R lines, for shock loa
ding along the low symmetry r direction, were obtained to evaluate our
earlier theoretical formulation regarding the response of R lines in
ruby crystals subjected to arbitrary deformations. The experimental re
sults show good agreement with the calculated values based on symmetry
adapted irreducible strains and, therefore, make a strong case for th
e predictive capability of the theoretical model. Additionally, the pa
rameters in the theory were augmented to incorporate the previously ob
served nonlinear shifts of the R lines for shock compression along the
c and a axis. With the general validation of our theoretical model, o
riented ruby chips can now be utilized in diamond anvil cell experimen
ts to obtain quantitative estimates of stress deviators at high pressu
res. These, in turn, can be used to evaluate material strength, and th
e role of nonhydrostatic stresses on sample response, at large compres
sions. (C) 1998 American Institute of Physics. [S0021-8979(98)07716-0]
.