An analytic theory has been developed to calculate the rise of electro
luminescence from bilayer light emitting diodes with internal energy b
arriers for bath majority and minority carriers upon applying a rectan
gular voltage pulse. Unless the mobility of the minority carriers-usua
lly electrons, instead, is less than or equal to 2 x 10(-7) cm(2)/V s,
onset of electroluminescence is governed by the growth of the interfa
cial charge densities and the concomitant redistribution of the electr
ic held inside the device rather than by charge carrier transport. The
crucial system parameters turn out to be the energy barriers that con
trol hole and electron injection. Good agreement with experiment is fo
und. (C) 1998 American Institute of Physics. [S0021-8979(98)08116-X].